2024 Acs macro letters - A library of fluorinated aryl diazomethanes were polymerized using BF3·OEt2 as a catalyst. The polymerization of 2,3,4,5,6-pentafluorophenyl diazomethane was found to be controlled, permitted chain extensions, and facilitated access to a series of block copolymers. Moreover, the polymer chains grew in one carbon increments (so …

 
How can single-chain polymer nanoparticles (SCNPs) be used to manipulate the mechanical properties of polymer networks? This article reports a novel approach to create multi-stimuli-responsive hydrogels by cross-linking SCNPs with dynamic covalent bonds. The resulting materials exhibit tunable elasticity, self-healing, and shape memory …. Acs macro letters

Already in the first volume of ACS Macro Letters, a study showed that the excess free energy of defects in lamella-forming diblock copolymers is on the order of 100 times the thermal energy unit, k B T. Thus, defects that are observed in experiments and simulations cannot be conceived as equilibrium fluctuations but arise in the course of the ...RETURN TO ISSUE PREV Letter NEXT. Functionalizable, Side Chain-Immolative Poly(benzyl ether)s. Yue Xiao. ... Cite this: ACS Macro Lett. 2019, 8, 4, 399–402. Publication Date (Web): March 26, 2019. Publication History. Received 19 February 2019; Accepted 22 March 2019; Published online 26 March 2019;In the past decade, photochemistry has emerged as a growing area in organic and polymer chemistry. Use of light to drive polymerization has advantages by imparting spatial and temporal control over the reaction. Photoinduced electron/energy transfer reversible addition–fragmentation chain transfer polymerization (PET-RAFT) has emerged as an excellent technique for developing well-defined ...While ACS Macro Letters was originally spun out of Macromolecules, the goal of the journal was to be the ACS Letters journal for all areas of polymer science. In 2014, Biomacromolecules stopped publishing Communications/Letters, and as such, ACS Macro Letters serves as the Letters journal for both communities. The last three years or so have ... ACS Macro Letters publishes research in all areas of contemporary soft matter science in which macromolecules play a key role, including nanotechnology, self-assembly, supramolecular chemistry, biomaterials, energy generation and storage, and renewable/sustainable materials. William J. Neary and Justin G. Kennemur * ACS Macro Letters 2019, 8, 1, 46-56 (Viewpoint) Publication Date (Web): December 20, 2018 Abstract Full text PDF …A library of fluorinated aryl diazomethanes were polymerized using BF3·OEt2 as a catalyst. The polymerization of 2,3,4,5,6-pentafluorophenyl diazomethane was found to be controlled, permitted chain extensions, and facilitated access to a series of block copolymers. Moreover, the polymer chains grew in one carbon increments (so …3 កុម្ភៈ 2014 ... ... ACS Macro Letters. The three-year term began January 1, 2014. As a member of the Editorial Advisory Board, Li works with the ACS ...Proteins have tremendous potential for vaccine development and disease treatment, but multiple extracellular and intracellular biological barriers must be overcome before they can exert specific biological functions in the target tissue. The use of polymers as carriers would greatly improve their bioavailability and therapeutic efficiency. Nevertheless, effective protein packaging and cell ...ACS Macro Letters is a peer-reviewed scientific journal published by the American Chemical Society. As of 2017, ACS Macro Letters has the highest impact factor of any …ACS Macro Letters is a peer-reviewed scientific journal published by the American Chemical Society. As of 2017, ACS Macro Letters has the highest impact factor of any …Whether you’re good at taking tests or not, they’re a part of the academic life at almost every level, from elementary school through graduate school. Fortunately, there are some things you can do to improve your test-taking abilities and a...Abstract. Spider silk exhibits a combination of outstanding tensile strength and extensibility unique among all synthetic and biogenic polymer fibers. It has thus generated great interest to understand protein-based high-toughness materials and inspired the design of similar synthetic materials. The unrivaled properties of silk fibers have been ...Open access pricing for ACS Publications journals - article processing charges and country discount information.We demonstrate a single-phase, two-way shape actuator that, in the absence of an external load, elongates upon cooling and reversibly contracts upon heating. In a simple and straightforward process, a partially cross-linked, semicrystalline poly(ε-caprolactone) (PCL) network is melted, stretched to several hundred percent strain, and …She is also currently the Chair-Elect of the ACS Polymeric Materials: Science and Engineering Division (2023) and was previously a member of the Macromolecules and ACS Macro Letters Editorial Advisory Board. Prof.Jun 11, 2012 · Vitrimers, strong organic glass formers, are covalent networks that are able to change their topology through thermoactivated bond exchange reactions. At high temperatures, vitrimers can flow and behave like viscoelastic liquids. At low temperatures, exchange reactions are very long and vitrimers behave like classical thermosets. The …This article is cited by 17 publications. Magnus Hansen-Felby, Martin Lahn Henriksen, Steen Uttrup Pedersen, Kim Daasbjerg. Postfunctionalization of Self-Immolative Poly(dithiothreitol) Using Steglich Esterification.ACS Macro Letters published several important papers on novel synthesis of naturally derived synthetic polysaccharides and glycopolymers. For example, Grinstaff and his colleagues have published a number of ACS Macro Letters on their polyamidosaccharides (PASs) over the years. PAS is a type of naturally derived synthetic polysaccharide, made ... Oct 25, 2023 · Submissions to ACS Macro Letters should justify clearly the rapid disclosure of the key elements of the study in both the cover letter and the manuscript. For more details, visit the journal website. Manuscript Types ACS Macro Letters is an online publication and predominantly publishes research Letters. The journal also publishes Viewpoints ... ACS Macro Letters 2019, 8 (8) , 973-978. DOI: 10.1021/acsmacrolett.9b00439. Chang-Geun Chae, In-Gyu Bak, Jae-Suk Lee. Utilization of a Kinetic Principle of the Sequence-Controlled Anionic Copolymerization of Isocyanates toward Polyisocyanate Copolymers Encoded with Multiple Monomer Sequences. ...ACS Macro Letters 2023, Article ASAP. Yang Ma, Ya-Nan Zhao, Xi-Man Yang, Jun-Fang Li, Xiao-Yan Wang, Yong Tang. SaBOX/Copper-Catalyzed Synthesis, Degradation, and Upcycling of a …Conventional cross-linked polymers cannot be reprocessed because of the presence of permanent covalent cross-links, preventing reuse and recycling. Covalent adaptable networks (CANs) employ dynamic covalent bonds that undergo dynamic reactions under external stimulus, allowing recyclability of these network materials. Hindered urea chemistry is one of the recently discovered dissociative ... Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2019, 8, 11, 1522-1527. ADVERTISEMENT. Wednesday, June 7. We are undergoing maintenance which may impact PDF downloads for some users. This update will complete shortly and we appreciate your patience while we improve the ACS Publications Platform. ... ACS …School of Materials Science and Engineering, Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, Research Center for Functional Biomaterials Engineering and Technology Guangdong, Guangzhou Key Laboratory of Flexible Electronic Materials and Wearable Devices, Sun Yat-Sen University, Guangzhou 510006, ChinaDynamic covalent bonds can be incorporated into polymer networks for a host of applications. In this Viewpoint, Evans and coworkers describe the outlook for this class of polymers and highlight key questions regarding how dynamic bonds impact self-assembly, viscoelasticity, and functionality of dynamic polymer networks. View the article.Conventional cross-linked polymers cannot be reprocessed because of the presence of permanent covalent cross-links, preventing reuse and recycling. Covalent adaptable networks (CANs) employ dynamic covalent bonds that undergo dynamic reactions under external stimulus, allowing recyclability of these network materials. Hindered urea chemistry is one of the recently discovered dissociative ... Surface-initiated, Cu0-mediated ATRP demonstrates an efficient, oxygen-tolerant process to functionalize 3D microporous supports in a controlled fashion, forming single and multiple brush gradients with a fully tunable composition. View the article.Dec 17, 2019 · Stereoselective copolymerization of vinyl ethers using a chiral BINOL-based phosphoric acid in combination with a titanium Lewis acid enabled the realization of semicrystalline thermoplastics with tunable thermomechanical properties. The broad substrate scope of the catalyst facilitated the copolymerization of structurally diverse monomers without sacrificing stereoselectivity. The method ... RETURN TO ISSUE PREV Letter NEXT. One-Pot Synthesis of Strong Anionic/Charge-Neutral Amphiphilic Block Copolymers. Théophile Pelras * ... Cite this: ACS Macro Lett. 2023, 12, 8, 1071–1078. Publication Date (Web): July 18, 2023. Publication History. Received 7 June 2023; Accepted 13 July 2023;Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2019, 8, 4, 399-402. ADVERTISEMENT. RETURN TO ISSUE PREV Letter NEXT. Functionalizable, Side Chain-Immolative Poly(benzyl ether)s. Yue Xiao. Yue Xiao. Institute of Chemical Biology and Nanomedicine, College of Chemistry and Chemical Engineering, Hunan …Mar 23, 2023 · 近期,复旦大学李卫华教授团队与北京航空航天大学蒋滢研究员团队、华东理工大学张良顺教授团队合作,设计了一个嵌段共聚物反向设计框架(图2),用于在高维空间中快速搜索目标自组装结构的稳定参数。. 整个方向设计流程是一个循环迭代的过程,框架 ...Correlation between Self-Folding Behavior of Amphiphilic Polymers and Their Molecular Flexibility. Masanori Nagao *. and. Yoshiko Miura *. ACS Macro Letters 2023, 12, 6, 733-737 (Letter) Publication Date (Web): …Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2019, 8, 11, 1522-1527. ADVERTISEMENT. Wednesday, June 7. We are undergoing maintenance which may impact PDF downloads for some users. This update will complete shortly and we appreciate your patience while we improve the ACS Publications Platform. ... ACS …Optical Tweezers Microrheology: From the Basics to Advanced Techniques and Applications. Rae M. Robertson-Anderson *. ACS Macro Letters 2018, 7, 8, 968-975 (Viewpoint) Publication Date (Web): August 5, 2018. Abstract.ACS Macro Letters (2015), 4 (3), 284-288 CODEN: AMLCCD; ISSN: 2161-1653. ( American Chemical Society ) Using the glucose derivs. -- isosorbide and glucarodilactone -- along with a castor oil deriv., 10-undecenoyl chloride, two monomers were synthesized: glucarodilactone undecenoate (GDLU) and isosorbide undecenoate (IU).We investigate the dynamics of polymers grafted to spherical nanoparticles in solution using hybrid molecular dynamics simulations with a coarse-grained solvent modeled via the multiparticle collision dynamics algorithm. The mean-square displacements of monomers near the surface of the nanoparticle exhibit a plateau on intermediate time scales, …Desilylation-Triggered Degradable Silylacetal Polymers Synthesized via Controlled Cationic Copolymerization of Trimethylsilyl Vinyl Ether and Cyclic Acetals. Ryusei Kato. , Arihiro Kanazawa *. , and. Sadahito Aoshima *. ACS Macro Letters 2019, 8, 11, 1498-1503 (Letter) Publication Date (Web): October 25, 2019.May 17, 2023 · With the trend toward lighter and thinner flexible electronics, developing foldable polymeric substrates that can withstand ultralow folding radiuses has become an urgent issue. Here, a strategy to develop polyimide (PI) films with excellent dynamic and static folding resistance under an ultralarge curvature through copolymerizing one …A schematic illustration of the incorporation of enantiomeric TFAE inducing it-PMMA with a predominantly one-handed helical conformation in the helical cavity of the st-PMMA upon stereocomplexation, thus giving an induced circular polarized luminescence. View the article.Submissions to ACS Macro Letters should justify clearly the rapid disclosure of the key elements of the study in both the cover letter and the manuscript. For more details, visit the journal website. Manuscript Types ACS Macro Letters is an online publication and predominantly publishes research Letters. The journal also publishes Viewpoints ...Side substitution is an effective method for the chemical modification and functionalization of linear polyesters. The presence of side groups can have a profound effect on the crystalline structure and phase transition of semicrystalline polyesters. Herein, we synthesized the long-spaced polyesters with −OH and −CH3 side groups and various methylene segment lengths and studied the effects ...RETURN TO ISSUE PREV Letter NEXT. Functionalizable, Side Chain-Immolative Poly(benzyl ether)s. Yue Xiao. ... Cite this: ACS Macro Lett. 2019, 8, 4, 399–402. Publication Date (Web): March 26, 2019. Publication History. Received 19 February 2019; Accepted 22 March 2019; Published online 26 March 2019;How can single-chain polymer nanoparticles (SCNPs) be used to manipulate the mechanical properties of polymer networks? This article reports a novel approach to create multi-stimuli-responsive hydrogels by cross-linking SCNPs with dynamic covalent bonds. The resulting materials exhibit tunable elasticity, self-healing, and shape memory …Already in the first volume of ACS Macro Letters, a study showed that the excess free energy of defects in lamella-forming diblock copolymers is on the order of 100 times the thermal energy unit, k B T. Thus, defects that are observed in experiments and simulations cannot be conceived as equilibrium fluctuations but arise in the course of the ...Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, XXXX, XXX, 974-979. ADVERTISEMENT. RETURN TO ARTICLES ASAP PREV Letter NEXT.Hydration-triggered anisotropic swelling behaviors of hydrogel microstructures can be utilized for the development of a stimuli-responsive smart and strong wet adhesive. Image courtesy of Hyun-Ha Park and Hoon Eui Jeong. View the article.Polymer-topology effects can alter technologically relevant properties when cyclic macromolecules are applied within diverse materials formulations. These include coatings, polymer networks, or nanostructures for delivering therapeutics. While substituting linear building blocks with cyclic analogues in commonly studied materials is itself of fundamental interest, an even more fascinating ...Our bodies are composed of soft tissues made of various proteins. In contrast, most hydrogels designed for biological applications are made of synthetic polymers. Recently, it is increasingly recognized that genetically synthesized proteins can be tailored as building blocks of hydrogels with biological, chemical, and mechanical …In today’s digital age, having a strong online presence is crucial for businesses, especially for ace online stores. With the increasing popularity of e-commerce, it’s important to ensure that your online store stands out from the competiti...ACS Macro Letters published several important papers on novel synthesis of naturally derived synthetic polysaccharides and glycopolymers. For example, Grinstaff and his colleagues have published a number of ACS Macro Letters on their polyamidosaccharides (PASs) over the years. PAS is a type of naturally derived synthetic polysaccharide, made ...Correlation between Self-Folding Behavior of Amphiphilic Polymers and Their Molecular Flexibility. Masanori Nagao *. and. Yoshiko Miura *. ACS Macro Letters 2023, 12, 6, 733-737 (Letter) Publication Date (Web): …ACS Macro Letters is a peer-reviewed scientific journal published by the American Chemical Society. As of 2017, ACS Macro Letters has the highest impact factor of any journal in the field of polymer science (6.131). [1] With the launch of ACS Macro Letters, all Communications to the Editor that were formerly published in Macromolecules will be ... ACS Macro Letters is a journal published by American Chemical Society.This journal covers the area[s] related to Inorganic Chemistry, Materials Chemistry, Organic Chemistry, Polymers and Plastics, etc.The coverage history of this journal is as follows: 2012-2022. The rank of this journal is 1796.This journal's impact score, h-index, …May 26, 2020 · Rapid, solvent-free synthesis of poly(1,4-butadiene) in ambient conditions is demonstrated by frontal ring-opening metathesis polymerization (FROMP) of 1,5-cyclooctadiene (COD). Furthermore, cross-linked copolymers with a wide range of tunable properties are readily prepared by FROMP of mixtures of COD and dicyclopentadiene …Whether you’re good at taking tests or not, they’re a part of the academic life at almost every level, from elementary school through graduate school. Fortunately, there are some things you can do to improve your test-taking abilities and a...The thermomechanical properties exhibited by synthetic macromolecules can be directly linked to their tacticity, or the relative stereochemistry of repeat units. The development of stereoselective coordination–insertion polymerization, for example, led to the discovery of isotactic polypropylene, now one of the most widely produced commodity ...Jul 3, 2023 · Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, XXXX, XXX, 986-992. ADVERTISEMENT. RETURN TO ARTICLES ASAP Letter NEXT. Directional Self-Assembly of Nanoparticles Coated with Thermoresponsive Block Copolymers and Charged Small Molecules. Ga-Hyun Kim. Ga-Hyun Kim.RETURN TO ARTICLES ASAP Letter NEXT. Dynamic Cross-Linked Polyethylene Networks with High Energy Storage and Electrical Damage Self-Healability. Zhen Li. Zhen Li. ... Cite this: ACS Macro Lett. 2023, 12, XXX, 1409–1415. Publication Date (Web): October 4, 2023. Publication History. Received 2 July 2023; Accepted 25 …ACS Macro Letters published several important papers on novel synthesis of naturally derived synthetic polysaccharides and glycopolymers. For example, Grinstaff and his colleagues have published a number of ACS Macro Letters on their polyamidosaccharides (PASs) over the years. PAS is a type of naturally derived synthetic polysaccharide, made ... Monophosphoniums as Effective Photoredox Organocatalysts for Visible Light-Regulated Cationic RAFT Polymerization. Zan Yang. , Jianxu Chen. , and. Saihu Liao *. ACS Macro Letters 2022, 11, 9, 1073-1078 (Letter) Publication Date (Web): August 19, 2022. Abstract.Macro environmental elements include technological, legal-political, economic, sociocultural and international variables. Examples of outside technological factors that impact organizations include changes to market demand and production pr...The study of mechanoresponsive properties of nanovesicles is essential to understand and regulate many physiological activities. The actual capillary number-dependent force-responsive performance of vesicles was revealed unprecedentedly at the nanoscale level. Polydiacetylene was found as a sensitive chromic mechanoresponsive …All manuscripts must be accompanied by a cover letter that contains clear and precise information about the submission and a paragraph explaining why the manuscript is appropriate for ACS Macro Letters, including a short summary highlighting the significance of the work, justifying the rapid Letter format, and its interest for a broad …100th Anniversary of Macromolecular Science Viewpoint: Re-Engineering Cellular Interfaces with Synthetic Macromolecules Using Metabolic Glycan Labeling. Ruben M. F. Tomás. and. Matthew I. Gibson *. ACS Macro Letters 2020, 9, 7, 991-1003 (Viewpoint) Publication Date (Web): June 25, 2020. Abstract. Full text.Thermal switches are of great importance to thermal management in a wide variety of applications. However, traditional thermal switches suffer from being large and having slow transition rates. To overcome these limitations, we took advantage of abrupt second-order phase transitions in thermoresponsive polymer aqueous solutions to enable fast thermal switching. While thermoresponsive polymers ... RETURN TO ARTICLES ASAP PREV Letter NEXT. Bridging the Monomer to Polymer Gap in Radical Polymer Design. Ying Tan. Ying Tan. ... Cite this: ACS Macro Lett. 2023, 12, XXX, 801–807. Publication Date (Web): May 31, 2023. Publication History. Received 20 February 2023; Accepted 25 May 2023;This tool can also be applied to predict composition in nondrifting polymerizations. Herein we supply this tool to the community, showcasing two recent examples of use to guide experimental design and understanding of heteropolymers (RHP). 10.1021/acsmacrolett.8b00813. mz8b00813_si_001.pdf (616.6 kb)Bilayer hydrogels encoded with smart functions have emerged as promising soft materials for engineered biological tissues and human-machine interfaces, due to the versatility and flexibility in designing their mechanical and chemical properties. However, conventional fabrication strategies often require multiple complicated steps to create an anisotropic bilayer structure with poor interfaces ...†Department of Chemistry and Biochemistry, University of Arizona, 1306 East University Boulevard, Tucson, Arizona 85721, United States § School of Chemical and Biological Engineering, The World Class University Program of Chemical Convergence for Energy and Environment, The National CRI Center for Intelligent Hybrids, and Center for Nanoparticle Research, Institute for Basic Research (IBS ... 3 កុម្ភៈ 2014 ... ... ACS Macro Letters. The three-year term began January 1, 2014. As a member of the Editorial Advisory Board, Li works with the ACS ...In today’s fast-paced business environment, efficiency is key. Every minute spent on repetitive and mundane tasks is a minute taken away from more important activities that could drive growth and innovation.Reaction Environment Effect on the Kinetics of Radical Thiol–Ene Polymerizations in the Presence of Amines and Thiolate Anions. Dillon Love. , Benjamin Fairbanks. , and. Christopher Bowman *. ACS Macro Letters 2020, 9, 2, 174-179 (Letter) Publication Date (Web): January 16, 2020. Abstract.21 កុម្ភៈ 2012 ... ACS Macro Letters創刊! ... アメリカ化学会(ACS)の高分子科学専門誌であるMacromoleculesのCommunications部分が独立して、高分子科学のCommunications専門 ...May 17, 2023 · Although in Nature sequence control is widely adopted to tune the structure and functions of biomacromolecules, it remains challenging and largely unexplored in synthetic macromolecular systems due to the difficulties in a precision synthesis, which impedes the understanding of the structure–property relationship in macromolecular …Stereoselective copolymerization of vinyl ethers using a chiral BINOL-based phosphoric acid in combination with a titanium Lewis acid enabled the realization of semicrystalline thermoplastics with tunable thermomechanical properties. The broad substrate scope of the catalyst facilitated the copolymerization of structurally diverse monomers without sacrificing stereoselectivity. The method ...Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, XXXX, XXX, 880-887. ADVERTISEMENT. RETURN TO ARTICLES ASAP Letter NEXT. Enhanced Dielectric Properties of All-Cellulose Composite Film via Modulating Hydroxymethyl Conformation and Hydrogen Bonding Network.Jul 6, 2023 · Cite this: ACS Macro Lett. 2023, 12, XXX, 1005–1011. Publication Date (Web) ... Get article recommendations from ACS based on references in your Mendeley library. Melting of crystals is an archetypical first order phase transition. Albeit extensive efforts, the molecular origin of this process in polymers is still not clear. Experiments are complicated by the tremendous change in mechanical properties and the occurrence of parasitic phenomena masking the genuine material response. Here, we present an experimental …The origin of the activated monomer mechanism (AMM) in cationic ring-opening polymerization (CROP) is described first. Then, conditions leading to the active chain end (ACE) mechanism and AMM are compared, as well as methods allowing to distinguish between these two mechanisms. These methods are based on the “ion trapping” of the …While ACS Macro Letters was originally spun out of Macromolecules, the goal of the journal was to be the ACS Letters journal for all areas of polymer science. In 2014, Biomacromolecules stopped publishing Communications/Letters, and as such, ACS Macro Letters serves as the Letters journal for both communities. The last three years or so have ...ACS Macro Letters welcomes submissions in all areas of contemporary soft matter science in which macromolecules play a key role, including nanotechnology, self-assembly, supramolecular chemistry, biomaterials and biomedical materials, membranes and separations, energy generation and storage, and renewable/sustainable materials.Surface coating is essential and critical to endow fiber materials with various functions for broad applications. However, it is still a great challenge to achieve a fast, fully covered, and robust surface coating on multiple fibers. In this work, a nanoscale surface coating with superior stability was rapidly and integrally formed on various fiber materials (such as Nylon mesh, nonwoven ...Herein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough …Jul 3, 2023 · Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, XXXX, XXX, 986-992. ADVERTISEMENT. RETURN TO ARTICLES ASAP Letter NEXT. Directional Self-Assembly of Nanoparticles Coated with Thermoresponsive Block Copolymers and Charged Small Molecules. Ga-Hyun Kim. Ga-Hyun Kim.May 19, 2023 · Nebulized lipid nanoparticles (LNPs) have been considered as potential therapies for genetic disease as well as infectious disease. However, the sensitivity of LNPs to high shear stress during the nebulization process results in loss of the integrity of the nanostructure and the capability of delivering active pharmaceutical ingredients. Herein …Mar 27, 2023 · Conjugated polymers (CPs) have been actively utilized as photocatalysts for hydrogen evolution due to their easy synthetic tunability to endow specific functionalities, including visible-light absorption, higher-lying LUMO energy for proton reduction, and sufficient photochemical stability. Enhancing interfacial surface and compatibility of hydrophobic CPs with hydrophilic water is the central ... Dec 17, 2019 · Stereoselective copolymerization of vinyl ethers using a chiral BINOL-based phosphoric acid in combination with a titanium Lewis acid enabled the realization of semicrystalline thermoplastics with tunable thermomechanical properties. The broad substrate scope of the catalyst facilitated the copolymerization of structurally diverse …Acs macro letters

100th Anniversary of Macromolecular Science Viewpoint: Re-Engineering Cellular Interfaces with Synthetic Macromolecules Using Metabolic Glycan Labeling. Ruben M. F. Tomás. and. Matthew I. Gibson *. ACS Macro Letters 2020, 9, 7, 991-1003 (Viewpoint) Publication Date (Web): June 25, 2020. Abstract. Full text.. Acs macro letters

acs macro letters

The thermomechanical properties exhibited by synthetic macromolecules can be directly linked to their tacticity, or the relative stereochemistry of repeat units. The development of stereoselective coordination–insertion polymerization, for example, led to the discovery of isotactic polypropylene, now one of the most widely produced commodity ...Mar 28, 2023 · The conventional hydration number, λ, of a polymer electrolyte membrane (PEM) is estimated by the gravimetric measurement of the total water uptake in the membrane. This is the overall water molecules divided by the number of ionic groups covering the water distribution from the macroscale to the molecular level. For a more precise evaluation of the local ion–water interactions and ion ... ACS Energy Letters, ACS Engineering Au, ACS Environmental Au, ACS ES&T Air, ACS ES&T ... ACS Macro Letters, ACS Materials Au, ACS Materials Letters, ACS ...School of Materials Science and Engineering, Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, Research Center for Functional Biomaterials Engineering and Technology Guangdong, Guangzhou Key Laboratory of Flexible Electronic Materials and Wearable Devices, Sun Yat-Sen University, Guangzhou 510006, ChinaRadical ring-opening polymerization (rROP) allows facile incorporation of labile groups (e.g., ester) into the main chain of vinyl polymers to obtain (bio)degradable materials. rROP has focused a lot of attention especially since the advent of reversible deactivation radical polymerization (RDRP) techniques and is still incredibly moving forward, as attested by the numerous achievements in ...Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, 12, 4, 481-486. ADVERTISEMENT. RETURN TO ISSUE PREV Letter NEXT. Microscopic Determination of the Local Hydration Number of Polymer Electrolyte Membranes Using SANS Partial Scattering Function Analysis.This study reveals the structural arrangements of polymers at the droplet interface, highlighting a notably more compact conformation at the interface compared to the …A schematic illustration of the incorporation of enantiomeric TFAE inducing it-PMMA with a predominantly one-handed helical conformation in the helical cavity of the st-PMMA upon stereocomplexation, thus giving an induced circular polarized luminescence. View the article. May 19, 2023 · Nebulized lipid nanoparticles (LNPs) have been considered as potential therapies for genetic disease as well as infectious disease. However, the sensitivity of LNPs to high shear stress during the nebulization process results in loss of the integrity of the nanostructure and the capability of delivering active pharmaceutical ingredients. Herein …Correlation between Self-Folding Behavior of Amphiphilic Polymers and Their Molecular Flexibility. Masanori Nagao *. and. Yoshiko Miura *. ACS Macro Letters 2023, 12, 6, 733-737 (Letter) Publication Date (Web): May 17, 2023. Abstract.This work demonstrates that “Van der Waals-driven self-healing” in lock-and-key copolymers is sensitive to the “sequence” of repeats and introduces strategies for the synthesis of lock-and-key copolymers that feature a balance of self-healing efficacy and improved mechanical properties such as stiffness, strength, and toughness. View the article.Choosing the right air conditioning unit is extremely important, especially if you live in an area that gets really hot during the summer months or if it’s hot all year round. The following tips can help ensure that you choose the right AC ...Theory of Spatial Gradients of Relaxation, Vitrification Temperature and Fragility of Glass-Forming Polymer Liquids Near Solid Substrates. Anh D. Phan *. and. Kenneth S. Schweizer *. ACS Macro Letters 2020, 9, 4, 448-453 (Letter) Publication Date (Web): March 13, 2020. Abstract.Examining the Impact of Relative Mechanophore Activity on the Selectivity of Ultrasound-Induced Mechanochemical Chain Scission. Anna C. Overholts. and. Maxwell J. Robb *. ACS Macro Letters 2022, 11, 6, 733-738 (Letter) Publication …ACS Macro Letters is a journal published by American Chemical Society.This journal covers the area[s] related to Inorganic Chemistry, Materials Chemistry, Organic Chemistry, Polymers and Plastics, etc.The coverage history of this journal is as follows: 2012-2022. The rank of this journal is 1796.This journal's impact score, h-index, …We demonstrate a single-phase, two-way shape actuator that, in the absence of an external load, elongates upon cooling and reversibly contracts upon heating. In a simple and straightforward process, a partially cross-linked, semicrystalline poly(ε-caprolactone) (PCL) network is melted, stretched to several hundred percent strain, and …Understanding the physicochemical properties of hydrogel surfaces and their molecular origins is important for their applications. In this paper, we elucidate the molecular origin of surface charges in double-network hydrogels synthesized by two-step sequential polymerization. Synthesis of hydrogels by free-radical polymerization does not fully complete the reaction, leaving a small number of ...Poly (β-Cyclodextrin) Prepared by Ring-Opening Metathesis Polymerization Enables Creation of Supramolecular Polymeric Networks. Mohammed Alaboalirat. and. John B. Matson *. ACS Macro Letters 2021, 10, 12, 1460-1466 (Letter) Publication Date (Web): November 8, 2021. Abstract.ACS Macro Letters (2015), 4 (3), 284-288 CODEN: AMLCCD; ISSN: 2161-1653. ( American Chemical Society ) Using the glucose derivs. -- isosorbide and glucarodilactone -- along with a castor oil deriv., 10-undecenoyl chloride, two monomers were synthesized: glucarodilactone undecenoate (GDLU) and isosorbide undecenoate (IU). Weak mechanical properties and excessive swelling due to high water content in hydrogels are two of the biggest challenges for their development in the field of bioelectronics. As an alternative, proposed diazirine-based hydrophobic CaproGlu adhesives can adhere to soft tissues, mimic tissue mechanical properties, cross-link in the presence of water, and provide electrical conductivity and ...Poly(vinyl phosphonic acid)-based double hydrophilic block copolymers by gadolinium ions are demonstrated to be the polymer of choice in the design of highly stable MRI contrast agents. Measurement of high magnetic relaxivities in vitro and in vivo magnetic resonance imaging on rats demonstrate the high potential of such polymeric assemblies. …Dynamic covalent bonds can be incorporated into polymer networks for a host of applications. In this Viewpoint, Evans and coworkers describe the outlook for this class of polymers and highlight key questions regarding how dynamic bonds impact self-assembly, viscoelasticity, and functionality of dynamic polymer networks. View the article. ACS Macro Letters (2015), 4 (3), 284-288 CODEN: AMLCCD; ISSN: 2161-1653. ( American Chemical Society ) Using the glucose derivs. -- isosorbide and glucarodilactone -- along with a castor oil deriv., 10-undecenoyl chloride, two monomers were synthesized: glucarodilactone undecenoate (GDLU) and isosorbide undecenoate (IU).Monophosphoniums as Effective Photoredox Organocatalysts for Visible Light-Regulated Cationic RAFT Polymerization. Zan Yang. , Jianxu Chen. , and. Saihu Liao *. ACS Macro Letters 2022, 11, 9, 1073-1078 (Letter) Publication Date (Web): August 19, 2022. Abstract. File Submission. Submit your own Manuscript PDF File—and provide your native LaTeX manuscript package as a ZIP archive. Compress the following into a single ZIP archive (.zip) file: Main body of the LaTeX document (i.e., a file ending with .tex or .ltx) All files referenced by the main LaTeX document (including other .tex files) Remember to ... ACS Macro Letters publishes research in all areas of contemporary soft matter science in which macromolecules play a key role, including nanotechnology, self-assembly, …Conventional cross-linked polymers cannot be reprocessed because of the presence of permanent covalent cross-links, preventing reuse and recycling. Covalent adaptable networks (CANs) employ dynamic covalent bonds that undergo dynamic reactions under external stimulus, allowing recyclability of these network materials. Hindered urea chemistry is one of the recently discovered dissociative ...ACS Macro Letters published several important papers on novel synthesis of naturally derived synthetic polysaccharides and glycopolymers. For example, Grinstaff and his colleagues have published a number of ACS Macro Letters on their polyamidosaccharides (PASs) over the years. PAS is a type of naturally derived synthetic polysaccharide, made ...ACS Macro Letters (2020), 9 (7), 1040-1045 CODEN: AMLCCD; ISSN: 2161-1653. ( American Chemical Society ) An original route to develop an advanced class of microgel emulsifiers contg. stimulable metallo-supramol. instead of frozen covalent cross-links is reported.3 កុម្ភៈ 2014 ... ... ACS Macro Letters. The three-year term began January 1, 2014. As a member of the Editorial Advisory Board, Li works with the ACS ...Aug 13, 2022 · File Submission. Submit your own Manuscript PDF File—and provide your native LaTeX manuscript package as a ZIP archive. Compress the following into a single ZIP archive (.zip) file: Main body of the LaTeX document (i.e., a file ending with .tex or .ltx) All files referenced by the main LaTeX document (including other .tex files) Remember to ...ACS Macro Letters : Editor-in-Chief: Stuart J Rowan. About the Journal. Open Access. Submission & Review. If you own a Robinair AC machine, you know how important it is to keep it in good working order. One of the key components of your machine is the wiring system. Without proper wiring, your machine won’t function as it should.This study reveals the structural arrangements of polymers at the droplet interface, highlighting a notably more compact conformation at the interface compared to the interior of the droplet. These findings also extend to condensates formed by natural intrinsically disordered proteins. View the article. 100th Anniversary of Macromolecular Science Viewpoint: Biological Stimuli-Sensitive Polymer Prodrugs and Nanoparticles for Tumor-Specific Drug Delivery. Huanli Sun. and. Zhiyuan Zhong *. ACS Macro Letters 2020, 9, 9, 1292-1302 (Viewpoint) Publication Date (Web): August 24, 2020. Abstract.Jun 22, 2022 · ACS Macro Letters (2019), 8 (12), 1546-1551 CODEN: AMLCCD; ISSN: 2161-1653. ( American Chemical Society ) Photo-ATRP has recently emerged as a powerful technique that allows for oxygen-tolerant polymns. and the prepn. of polymers with low dispersity and high end-group fidelity. 弊社で制作しました東京理科大学 青木大亮先生よりご依頼のカバーアートが、アメリカ化学会発行の学術雑誌 ACS.Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2023, XXXX, XXX, 986-992. ADVERTISEMENT. RETURN TO ARTICLES ASAP Letter NEXT.According to TGA analysis, heating for 12 h at 180, 200, and 220 °C, gave 30%, 73%, and 91% depolymerization. (30) Herein, we report the bulk depolymerization of PMMA and PBMA by the ATRP process. This approach employs chloro-terminated PBMA and PMMA (PBMA-Cl and PMMA-Cl; all experimental information and characterization details about the ...LetPub整理了最新的ACS Macro Letters 期刊投稿经验, 期刊官方投稿网址,影响因子,审稿周期/时间,研究方向,SCI期刊分区,中国作者发表的文章等信息, 以供中国作者 ...In today’s fast-paced business environment, efficiency is key. Every minute spent on repetitive and mundane tasks is a minute taken away from more important activities that could drive growth and innovation.10 មិថុនា 2022 ... ... ACS Macro Letters期刊上。 在材料防污涂层领域,聚乙二醇(PEG)因其优异的水溶性、抗吸附性及生物相容性受到广泛青睐,当 PEG 附着于材料表面时可 ...LetPub整理了最新的ACS Macro Letters 期刊投稿经验, 期刊官方投稿网址,影响因子,审稿周期/时间,研究方向,SCI期刊分区,中国作者发表的文章等信息, 以供中国作者 ...Jan 10, 2023 · She is also currently the Chair-Elect of the ACS Polymeric Materials: Science and Engineering Division (2023) and was previously a member of the Macromolecules and ACS Macro Letters Editorial Advisory Board. Prof. Monophosphoniums as Effective Photoredox Organocatalysts for Visible Light-Regulated Cationic RAFT Polymerization. Zan Yang. , Jianxu Chen. , and. Saihu Liao *. ACS Macro Letters 2022, 11, 9, 1073-1078 (Letter) Publication Date (Web): August 19, 2022. Abstract. Stereospecific Living Cationic Polymerization of N -Vinylcarbazole through the Design of ZnCl 2 -Derived Counteranions. Hironobu Watanabe. , Arihiro Kanazawa. , and. Sadahito Aoshima *. ACS Macro Letters 2017, 6, 4, 463-467 …ACS Macro Letters (2015), 4 (3), 284-288 CODEN: AMLCCD; ISSN: 2161-1653. ( American Chemical Society ) Using the glucose derivs. -- isosorbide and glucarodilactone -- along with a castor oil deriv., 10-undecenoyl chloride, two monomers were synthesized: glucarodilactone undecenoate (GDLU) and isosorbide undecenoate (IU).Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2017 6 11 1217-1222. Abstract. Biodegradable nanoarchitectures, with well-defined morphological features, ... ACS Macro Letters 2018, 7 (5) , 546-550. ...View the article. Download Cover In this issue: Viewpoint Letters Mastheads Sort By: Viewpoint Chemical Approaches to Dynamically Modulate the Properties of Synthetic Matrices Paige J. LeValley and April M. Kloxin * ACS Macro Letters 2019, 8, 1, 7-16 (Viewpoint) Publication Date (Web): December 22, 2018 Abstract Full text PDF ABSTRACTIn today’s competitive job market, standing out from the crowd is essential. While many job seekers focus solely on crafting the perfect resume and acing the interview, they often overlook a crucial step in the post-interview process – send...Dec 21, 2021 · The exciting and rapidly expanding field of mechanochemistry is at the very forefront of sustainable synthesis whilst also allowing greatly simplified experimental procedures and interesting alternative reactivity. For the first time, ring-opening copolymerization was performed via mechanochemistry. Highly efficient (co)polymerizations were achieved in a ball-milling system using monomers ... Jun 22, 2022 · ACS Macro Letters (2019), 8 (12), 1546-1551 CODEN: AMLCCD; ISSN: 2161-1653. ( American Chemical Society ) Photo-ATRP has recently emerged as a powerful technique that allows for oxygen-tolerant polymns. and the prepn. of polymers with low dispersity and high end-group fidelity. Dec 17, 2019 · Stereoselective copolymerization of vinyl ethers using a chiral BINOL-based phosphoric acid in combination with a titanium Lewis acid enabled the realization of semicrystalline thermoplastics with tunable thermomechanical properties. The broad substrate scope of the catalyst facilitated the copolymerization of structurally diverse …Conventional cross-linked polymers cannot be reprocessed because of the presence of permanent covalent cross-links, preventing reuse and recycling. Covalent adaptable networks (CANs) employ dynamic covalent bonds that undergo dynamic reactions under external stimulus, allowing recyclability of these network materials. Hindered urea chemistry is one of the recently discovered dissociative ...We demonstrate a single-phase, two-way shape actuator that, in the absence of an external load, elongates upon cooling and reversibly contracts upon heating. In a simple and straightforward process, a partially cross-linked, semicrystalline poly(ε-caprolactone) (PCL) network is melted, stretched to several hundred percent strain, and …ACS Macro Letters is a peer-reviewed scientific journal published by the American Chemical Society. As of 2017, ACS Macro Letters has the highest impact factor of any journal in the field of polymer science (6.131). With the launch of ACS Macro Letters, all Communications to the Editor that were formerly published in Macromolecules will be ...Dynamic polymer hydrogels with an environmental adaptive self-healing ability and dual responsive sol–gel transitions were prepared by combining acylhydrazone and disulfide bonds together in the same system. The hydrogel can automatically repair damage to it under both acidic (pH 3 and 6) and basic (pH 9) conditions through acylhydrazone …ACS Macro Letters : Editor-in-Chief: Stuart J Rowan. About the Journal. Open Access. Submission & Review. 18 កក្កដា 2023 ... 弊社で制作しました日本大学 伊掛浩輝先生、原秀太先生よりご依頼のカバーアートがアメリカ化学会発行の学術雑誌 A.Mar 24, 2021 · In the past decade, photochemistry has emerged as a growing area in organic and polymer chemistry. Use of light to drive polymerization has advantages by imparting spatial and temporal control over the reaction. Photoinduced electron/energy transfer reversible addition–fragmentation chain transfer polymerization (PET-RAFT) has …Surface-initiated, Cu0-mediated ATRP demonstrates an efficient, oxygen-tolerant process to functionalize 3D microporous supports in a controlled fashion, forming single and multiple brush gradients with a fully tunable composition. View the article.Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2019, 8, 11, 1522-1527. ADVERTISEMENT. Wednesday, June 7. We are undergoing maintenance which may impact PDF downloads for some users. This update will complete shortly and we appreciate your patience while we improve the ACS Publications Platform. ... ACS …Mar 27, 2023 · Van der Waals-driven self-healing in copolymers with “lock-and-key” architecture has emerged as a concept to endow engineering-type polymers with the capacity to recover from structural damage. Complicating the realization of “lock-and-key”-enabled self-healing is the tendency of copolymers to form nonuniform sequence …Oct 25, 2023 · Ensure that any symbols and abbreviations used in the text agree with those in the artwork. Authors are required to ensure that similar figures have similar resolution and quality (all black and white figures should have resolution similar to each other; all color figures should have resolution similar to each other). ACS Macro Lett. All Publications/Website. ... RETURN TO ISSUE PREV Letter NEXT. Thermal Transformation of Polyacrylonitrile Accelerated by the Formation of Ultrathin Nanosheets in a …ACS Macro Letters has been certified as a transformative journal by cOAlition S, committing to a transition to 100% open access in the future. If your research funder has signed Plan S, your open access charges may be covered by your funder through December 31, 2024. Please visit the ACS Open Science website for more …Conventional cross-linked polymers cannot be reprocessed because of the presence of permanent covalent cross-links, preventing reuse and recycling. Covalent adaptable networks (CANs) employ dynamic covalent bonds that undergo dynamic reactions under external stimulus, allowing recyclability of these network materials. Hindered urea chemistry is one of the recently discovered dissociative ...According to TGA analysis, heating for 12 h at 180, 200, and 220 °C, gave 30%, 73%, and 91% depolymerization. (30) Herein, we report the bulk depolymerization of PMMA and PBMA by the ATRP process. This approach employs chloro-terminated PBMA and PMMA (PBMA-Cl and PMMA-Cl; all experimental information and characterization details about the ...In today’s fast-paced business environment, efficiency is key. Every minute spent on repetitive and mundane tasks is a minute taken away from more important activities that could drive growth and innovation.Download Hi-Res Image Download to MS-PowerPoint Cite This: ACS Macro Lett. 2019, 8, 4, 399-402. ADVERTISEMENT. RETURN TO ISSUE PREV Letter NEXT. Functionalizable, Side Chain-Immolative Poly(benzyl ether)s. Yue Xiao. Yue Xiao. Institute of Chemical Biology and Nanomedicine, College of Chemistry and Chemical Engineering, Hunan …Oct 25, 2023 · Ensure that any symbols and abbreviations used in the text agree with those in the artwork. Authors are required to ensure that similar figures have similar resolution and quality (all black and white figures should have resolution similar to each other; all color figures should have resolution similar to each other). May 17, 2023 · Although in Nature sequence control is widely adopted to tune the structure and functions of biomacromolecules, it remains challenging and largely unexplored in synthetic macromolecular systems due to the difficulties in a precision synthesis, which impedes the understanding of the structure–property relationship in macromolecular …Triboluminescent polymer films were obtained by blending common luminophores and polymers, showing emission in response to friction or rubbing through a layer of inert material via triboelectrification-induced excitation of the luminophore. View the article.Anthony Delmonico , Gregory Denbeaux , Shaoyi Jiang , and Christopher K. Ober * ACS Macro Letters 2022, 11, 9, 1049-1054 (Letter) Publication Date (Web): August 10, 2022 …温馨提示:您使用的IP地址【40.79.186.179】请求期刊信息系统页面数据过于频繁,请稍后再试!This study compares the scattering signatures of two polymer electrolytes (PPM/TFSI and PEO/TFSI). The combination of X-ray scattering and computer simulation provides a powerful tool to accurately identify and understand the ion solvation structure. View the article.Hydration-triggered anisotropic swelling behaviors of hydrogel microstructures can be utilized for the development of a stimuli-responsive smart and strong wet adhesive. Image courtesy of Hyun-Ha Park and Hoon Eui Jeong. View the article.RETURN TO ISSUE PREV Letter NEXT. Hydrazone-Based Amphiphilic Brush Polymer for Fast Endocytosis and ROS-Active Drug Release. Sicheng Tang * Sicheng Tang. ... Cite this: ACS Macro Lett. 2023, 12, 5, 639–645. Publication Date (Web): April 27, 2023. Publication History. Received 21 March 2023; Accepted 25 April 2023;. Easternhoneys login